Friday, October 10, 2014

Show how you would accomplish the following synthetic transformations. Show all intermediates.

Show how you would accomplish the following synthetic transformations. Show all intermediates.

(a) 2,2-dibromobutane → but-1-yne

(b) 2,2-dibromobutane → but-2-yne

(c) but-1-yne → oct-3-yne

(d) trans-hex-2-ene → hex-2-yne

(e) 2,2-dibromohexane → hex-1-yne

(f) cyclodecyne → cis-cyclodecene

(g) cyclodecyne → trans-cyclodecene

(h) hex-1-yne → hexan-2-one, CH3COCH2CH2CH2CH3

(i) hex-1-yne → hexanal, CH3(CH2)4CHO

(j) trans-hex-2-ene → cis-hex-2-ene

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